Randolph Thummel
Title | Professor |
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Institution | University of Houston |
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Department | Chemistry |
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Address | 4800 Calhoun Rd Houston TX 77004
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Phone | 713-743-2734 |
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vCard | Download vCard |
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Bibliographic
Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications.
Faculty can login to make corrections and additions.
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Mane VS, Kumbhar AS, Thummel RP. A ruthenium water oxidation catalyst containing a bipyridine glycoluril ligand. Dalton Trans. 2017 Sep 18. PMID: 28920990.
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Moonshiram D, Pineda-Galvan Y, Erdman D, Palenik M, Zong R, Thummel R, Pushkar Y. Uncovering the Role of Oxygen Atom Transfer in Ru-Based Catalytic Water Oxidation. J Am Chem Soc. 2016 Dec 07; 138(48):15605-15616. PMID: 27802032.
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Tong L, Thummel RP. Mononuclear ruthenium polypyridine complexes that catalyze water oxidation. Chem Sci. 2016 Nov 01; 7(11):6591-6603. PMID: 28567250.
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Loftus LM, White JK, Albani BA, Kohler L, Kodanko JJ, Thummel RP, Dunbar KR, Turro C. New Ru(II) Complex for Dual Activity: Photoinduced Ligand Release and (1)O2 Production. Chemistry. 2016 Mar 07; 22(11):3704-8. PMID: 26715085; PMCID: PMC4775357.
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Wickramasinghe LD, Zhou R, Zong R, Vo P, Gagnon KJ, Thummel RP. Iron Complexes of Square Planar Tetradentate Polypyridyl-Type Ligands as Catalysts for Water Oxidation. J Am Chem Soc. 2015 Oct 21; 137(41):13260-3. PMID: 26425866.
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Tong L, Kopecky A, Zong R, Gagnon KJ, Ahlquist MS, Thummel RP. Light-Driven Proton Reduction in Aqueous Medium Catalyzed by a Family of Cobalt Complexes with Tetradentate Polypyridine-Type Ligands. Inorg Chem. 2015 Aug 17; 54(16):7873-84. PMID: 26213196.
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Golec B, Kijak M, Vetokhina V, Gorski A, Thummel RP, Herbich J, Waluk J. Solvent-Induced Changes in Photophysics and Photostability of Indole-Naphthyridines. J Phys Chem B. 2015 Jun 18; 119(24):7283-93. PMID: 25574590.
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Tong L, Zong R, Zhou R, Kaveevivitchai N, Zhang G, Thummel RP. Ruthenium catalysts for water oxidation involving tetradentate polypyridine-type ligands. Faraday Discuss. 2015; 185:87-104. PMID: 26426357.
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Bohne C, Pan Q, Ceroni P, Börjesson K, Rohacova J, Lewis F, Vlcek A, Bassani DM, Würthner F, Sartorel A, de Silva AP, Nocera D, Scandola F, Lemon C, Allain C, Brudvig GW, Marchesan S, Sundstrom V, Campagna S, Sheehan SW, Plötz PA, Monti F, Kelly JM, Gibson E, Maneiro M, Harriman A, Ruggi A, Galoppini E, Thummel R, Weinstein J, Vos J, Ishitani O, Gust D, Díaz-Moscoso A. Natural and artificial photosynthesis: general discussion. Faraday Discuss. 2015; 185:187-217. PMID: 26608169.
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Fransted KA, Jackson NE, Zong R, Mara MW, Huang J, Harpham MR, Shelby ML, Thummel RP, Chen LX. Ultrafast structural dynamics of Cu(I)-bicinchoninic acid and their implications for solar energy applications. J Phys Chem A. 2014 Nov 13; 118(45):10497-506. PMID: 25015003.
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Muckerman JT, Kowalczyk M, Badiei YM, Polyansky DE, Concepcion JJ, Zong R, Thummel RP, Fujita E. New water oxidation chemistry of a seven-coordinate ruthenium complex with a tetradentate polypyridyl ligand. Inorg Chem. 2014 Jul 07; 53(13):6904-13. PMID: 24911180.
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Tong L, Zong R, Thummel RP. Visible light-driven hydrogen evolution from water catalyzed by a molecular cobalt complex. J Am Chem Soc. 2014 Apr 02; 136(13):4881-4. PMID: 24635104.
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Kohler L, Kaveevivitchai N, Zong R, Thummel RP. Component analysis of dyads designed for light-driven water oxidation. Inorg Chem. 2014 Jan 21; 53(2):912-21. PMID: 24364791.
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Lincoln R, Kohler L, Monro S, Yin H, Stephenson M, Zong R, Chouai A, Dorsey C, Hennigar R, Thummel RP, McFarland SA. Exploitation of long-lived 3IL excited states for metal-organic photodynamic therapy: verification in a metastatic melanoma model. J Am Chem Soc. 2013 Nov 13; 135(45):17161-75. PMID: 24127659.
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Kaveevivitchai N, Kohler L, Zong R, El Ojaimi M, Mehta N, Thummel RP. A Ru(II) bis-terpyridine-like complex that catalyzes water oxidation: the influence of steric strain. Inorg Chem. 2013 Sep 16; 52(18):10615-22. PMID: 23987471.
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Lewandowska-Andralojc A, Polyansky DE, Zong R, Thummel RP, Fujita E. Enabling light-driven water oxidation via a low-energy RuIV=O intermediate. Phys Chem Chem Phys. 2013 Sep 07; 15(33):14058-68. PMID: 23860663.
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Badiei YM, Polyansky DE, Muckerman JT, Szalda DJ, Haberdar R, Zong R, Thummel RP, Fujita E. Water oxidation with mononuclear ruthenium(II) polypyridine complexes involving a direct Ru(IV)-O pathway in neutral and alkaline media. Inorg Chem. 2013 Aug 05; 52(15):8845-50. PMID: 23837911.
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Palmer AM, Peña B, Sears RB, Chen O, El Ojaimi M, Thummel RP, Dunbar KR, Turro C. Cytotoxicity of cyclometallated ruthenium complexes: the role of ligand exchange on the activity. Philos Trans A Math Phys Eng Sci. 2013 Jul 28; 371(1995):20120135. PMID: 23776296.
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Vetokhina V, Kijak M, Lipinska TM, Thummel RP, Sepiol J, Waluk J, Herbich J. Spectroscopy and photophysics of bifunctional proton donor-acceptor indole derivatives. J Phys Chem A. 2013 Jun 13; 117(23):4898-906. PMID: 23682822.
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Sears RB, Joyce LE, Ojaimi M, Gallucci JC, Thummel RP, Turro C. Photoinduced ligand exchange and DNA binding of cis-[Ru(phpy)(phen)(CH3CN)2]+ with long wavelength visible light. J Inorg Biochem. 2013 Apr; 121:77-87. PMID: 23353083.
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Carolan AN, Cockrell GM, Williams NJ, Zhang G, VanDerveer DG, Lee HS, Thummel RP, Hancock RD. Selectivity of the highly preorganized tetradentate ligand 2,9-di(pyrid-2-yl)-1,10-phenanthroline for metal ions in aqueous solution, including lanthanide(III) ions and the uranyl(VI) cation. Inorg Chem. 2013 Jan 07; 52(1):15-27. PMID: 23231454.
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Gorski A, Gawinkowski S, Herbich J, Krauss O, Brutschy B, Thummel RP, Waluk J. 1H-pyrrolo[3,2-h]quinoline: a benchmark molecule for reliable calculations of vibrational frequencies, IR intensities, and Raman activities. J Phys Chem A. 2012 Dec 06; 116(48):11973-86. PMID: 23134592.
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Kaveevivitchai N, Chitta R, Zong R, El Ojaimi M, Thummel RP. A molecular light-driven water oxidation catalyst. J Am Chem Soc. 2012 Jul 04; 134(26):10721-4. PMID: 22698450.
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Carolan AN, Mroz AE, El Ojaimi M, VanDerveer DG, Thummel RP, Hancock RD. Metal-ion-complexing properties of 2-(pyrid-2'-yl)-1,10-phenanthroline, a more preorganized analogue of terpyridyl. A crystallographic, fluorescence, and thermodynamic study. Inorg Chem. 2012 Mar 05; 51(5):3007-15. PMID: 22356117.
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Kaveevivitchai N, Zong R, Tseng HW, Chitta R, Thummel RP. Further observations on water oxidation catalyzed by mononuclear Ru(II) complexes. Inorg Chem. 2012 Mar 05; 51(5):2930-9. PMID: 22339431.
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Zong R, Wang B, Thummel RP. trans-[Ru(II)(dpp)Cl2]: a convenient reagent for the preparation of heteroleptic Ru(dpp) complexes, where dpp is 2,9-di(pyrid-2'-yl)-1,10-phenanthroline. Inorg Chem. 2012 Mar 05; 51(5):3179-85. PMID: 22324974.
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Cohen BW, Polyansky DE, Achord P, Cabelli D, Muckerman JT, Tanaka K, Thummel RP, Zong R, Fujita E. Steric effect for proton, hydrogen-atom, and hydride transfer reactions with geometric isomers of NADH-model ruthenium complexes. Faraday Discuss. 2012; 155:129-44; discussion 207-22. PMID: 22470971.
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Boyer JL, Polyansky DE, Szalda DJ, Zong R, Thummel RP, Fujita E. Effects of a proximal base on water oxidation and proton reduction catalyzed by geometric isomers of [Ru(tpy)(pynap)(OH2)]2+. Angew Chem Int Ed Engl. 2011 Dec 23; 50(52):12600-4. PMID: 22057468.
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El Ojaimi M, Thummel RP. Polydentate analogues of 8-hydroxyquinoline and their complexes with ruthenium. Inorg Chem. 2011 Nov 07; 50(21):10966-73. PMID: 21985103.
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Polyansky DE, Muckerman JT, Rochford J, Zong R, Thummel RP, Fujita E. Water oxidation by a mononuclear ruthenium catalyst: characterization of the intermediates. J Am Chem Soc. 2011 Sep 21; 133(37):14649-65. PMID: 21815653.
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Hamilton JM, Whitehead JR, Williams NJ, El Ojaimi M, Thummel RP, Hancock RD. Metal ion complexing properties of dipyridoacridine, a highly preorganized tridentate homologue of 1,10-phenanthroline. Inorg Chem. 2011 Apr 18; 50(8):3785-90. PMID: 21413728.
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Kyrychenko A, Wu F, Thummel RP, Waluk J, Ladokhin AS. Partitioning and localization of environment-sensitive 2-(2'-pyridyl)- and 2-(2'-pyrimidyl)-indoles in lipid membranes: a joint refinement using fluorescence measurements and molecular dynamics simulations. J Phys Chem B. 2010 Oct 28; 114(42):13574-84. PMID: 20925327; PMCID: PMC4470561.
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Cohen BW, Polyansky DE, Zong R, Zhou H, Ouk T, Cabelli DE, Thummel RP, Fujita E. Differences of pH-dependent mechanisms on generation of hydride donors using Ru(II) complexes containing geometric isomers of NAD+ model ligands: NMR and radiolysis studies in aqueous solution. Inorg Chem. 2010 Sep 06; 49(17):8034-44. PMID: 20687532.
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Sun Y, El Ojaimi M, Hammitt R, Thummel RP, Turro C. Effect of ligands with extended p-system on the photophysical properties of Ru(II) complexes. J Phys Chem B. 2010 Nov 18; 114(45):14664-70. PMID: 20545332.
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Zong R, Zhang G, Eliseeva SV, Bünzli JC, Thummel RP. Eu(III) complexes of tetradentate ligands related to 2,9-di(pyrid-2'-yl)-1,10-phenanthroline and 2,2'-bi-1,10-phenanthroline. Inorg Chem. 2010 May 17; 49(10):4657-64. PMID: 20392073.
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Vetokhina V, Kijak M, Wiosna-Salyga G, Thummel RP, Herbich J, Waluk J. On the origin of fluorescence quenching of pyridylindoles by hydroxylic solvents. Photochem Photobiol Sci. 2010 Jul 30; 9(7):923-30. PMID: 20445933.
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Monro S, Scott J, Chouai A, Lincoln R, Zong R, Thummel RP, McFarland SA. Photobiological activity of Ru(II) dyads based on (pyren-1-yl)ethynyl derivatives of 1,10-phenanthroline. Inorg Chem. 2010 Mar 15; 49(6):2889-900. PMID: 20146527.
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Wiosna-Salyga G, Nosenko Y, Kijak M, Thummel RP, Brutschy B, Waluk J. Structure and hydrogen-bond vibrations of water complexes of azaaromatic compounds: 7-(3'-pyridyl)indole. J Phys Chem A. 2010 Mar 11; 114(9):3270-9. PMID: 20039720.
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Zhao R, Hammitt R, Thummel RP, Liu Y, Turro C, Snapka RM. Nuclear targets of photodynamic tridentate ruthenium complexes. Dalton Trans. 2009 Dec 28; (48):10926-31. PMID: 20023923.
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Singh AN, Thummel RP. 1,5-Naphthyridine as a new linker for the construction of bridging ligands and their corresponding Ru(II) complexes. Inorg Chem. 2009 Jul 20; 48(14):6459-70. PMID: 19530693.
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Kumaresan D, Thummel RP, Bura T, Ulrich G, Ziessel R. Color tuning in new metal-free organic sensitizers (Bodipys) for dye-sensitized solar cells. Chemistry. 2009 Jun 22; 15(26):6335-9. PMID: 19462381.
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Liu Y, Hammitt R, Lutterman DA, Joyce LE, Thummel RP, Turro C. Ru(II) complexes of new tridentate ligands: unexpected high yield of sensitized 1O2. Inorg Chem. 2009 Jan 05; 48(1):375-85. PMID: 19035764.
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Tseng HW, Zong R, Muckerman JT, Thummel R. Mononuclear ruthenium(II) complexes that catalyze water oxidation. Inorg Chem. 2008 Dec 15; 47(24):11763-73. PMID: 19006384.
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Mudadu MS, Singh AN, Thummel RP. Preparation and study of 1,8-di(pyrid-2'-yl)carbazoles. J Org Chem. 2008 Sep 05; 73(17):6513-20. PMID: 18666796.
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Zong R, Zhou H, Thummel RP. Direct access to 4-carboxy-1,8-naphthyridines and related compounds through Pfitzinger-type chemistry. J Org Chem. 2008 Jun 06; 73(11):4334-7. PMID: 18461999.
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Deng Z, Tseng HW, Zong R, Wang D, Thummel R. Preparation and study of a family of dinuclear Ru(II) complexes that catalyze the decomposition of water. Inorg Chem. 2008 Mar 17; 47(6):1835-48. PMID: 18330974.
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Nosenko Y, Kunitski M, Riehn C, Thummel RP, Kyrychenko A, Herbich J, Waluk J, Brutschy B. Separation of different hydrogen-bonded clusters by femtosecond UV-ionization-detected infrared spectroscopy: 1H-pyrrolo[3,2-h]quinoline.(H2O)(n=1,2) complexes. J Phys Chem A. 2008 Feb 14; 112(6):1150-6. PMID: 18215027.
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Zhang G, Zong R, Tseng HW, Thummel RP. Ru(II) complexes of tetradentate ligands related to 2,9-di(pyrid-2'-yl)-1,10-phenanthroline. Inorg Chem. 2008 Feb 04; 47(3):990-8. PMID: 18183971.
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Cockrell GM, Zhang G, VanDerveer DG, Thummel RP, Hancock RD. Enhanced metal ion selectivity of 2,9-di-(pyrid-2-yl)-1,10-phenanthroline and its use as a fluorescent sensor for cadmium(II). J Am Chem Soc. 2008 Jan 30; 130(4):1420-30. PMID: 18177045.
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Nosenko Y, Wiosna-Salyga G, Kunitski M, Petkova I, Singh A, Buma WJ, Thummel RP, Brutschy B, Waluk J. Proton transfer with a twist? Femtosecond dynamics of 7-(2-pyridyl)indole in condensed phase and in supersonic jets. Angew Chem Int Ed Engl. 2008; 47(32):6037-40. PMID: 18604789.
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Abrahamsson M, Becker HC, Hammarström L, Bonnefous C, Chamchoumis C, Thummel RP. Six-membered ring chelate complexes of Ru(II): structural and photophysical effects. Inorg Chem. 2007 Nov 26; 46(24):10354-64. PMID: 17975915.
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Petkova I, Mudadu MS, Singh A, Thummel RP, van Stokkum IH, Buma WJ, Waluk J. Structure and photophysics of 2-(2'-pyridyl)benzindoles: the role of intermolecular hydrogen bonds. J Phys Chem A. 2007 Nov 15; 111(45):11400-9. PMID: 17935307.
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Liu Y, Hammitt R, Lutterman DA, Thummel RP, Turro C. Marked differences in light-switch behavior of Ru(II) complexes possessing a tridentate DNA intercalating ligand. Inorg Chem. 2007 Jul 23; 46(15):6011-21. PMID: 17567125.
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Nosenko Y, Kyrychenko A, Thummel RP, Waluk J, Brutschy B, Herbich J. Fluorescence quenching in cyclic hydrogen-bonded complexes of 1H-pyrrolo[3,2-h]quinoline with methanol: cluster size effect. Phys Chem Chem Phys. 2007 Jul 07; 9(25):3276-85. PMID: 17579736.
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Kijak M, Nosenko Y, Singh A, Thummel RP, Waluk J. Mode-selective excited-state proton transfer in 2-(2'-pyridyl)pyrrole isolated in a supersonic jet. J Am Chem Soc. 2007 Mar 14; 129(10):2738-9. PMID: 17305339.
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Kukrek A, Wang D, Hou Y, Zong R, Thummel R. Photosensitizers containing the 1,8-naphthyridyl moiety and their use in dye-sensitized solar cells. Inorg Chem. 2006 Dec 11; 45(25):10131-7. PMID: 17140219.
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Mudadu MS, Singh A, Thummel RP. 7-Pyridylindoles: synthesis, structure, and properties. J Org Chem. 2006 Sep 29; 71(20):7611-7. PMID: 16995665.
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Nosenko Y, Kunitski M, Thummel RP, Kyrychenko A, Herbich J, Waluk J, Riehn C, Brutschy B. Detection and structural characterization of clusters with ultrashort-lived electronically excited states: IR absorption detected by femtosecond multiphoton ionization. J Am Chem Soc. 2006 Aug 09; 128(31):10000-1. PMID: 16881614.
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Zong R, Wang D, Hammitt R, Thummel RP. Synthetic approaches to polypyridyl bridging ligands with proximal multidentate binding sites. J Org Chem. 2006 Jan 06; 71(1):167-75. PMID: 16388632.
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Bark T, Thummel RP. [1,10]-Phenanthrolin-2-yl ketones and their coordination chemistry. Inorg Chem. 2005 Nov 28; 44(24):8733-9. PMID: 16296827.
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Zong R, Thummel RP. A new family of Ru complexes for water oxidation. J Am Chem Soc. 2005 Sep 21; 127(37):12802-3. PMID: 16159265.
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Zong R, Thummel RP. 2,2';9',2''-Ter[1,10]phenanthroline. Inorg Chem. 2005 Aug 22; 44(17):5984-6. PMID: 16097816.
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Chouai A, Wicke SE, Turro C, Bacsa J, Dunbar KR, Wang D, Thummel RP. Ruthenium(II) complexes of 1,12-diazaperylene and their interactions with DNA. Inorg Chem. 2005 Aug 22; 44(17):5996-6003. PMID: 16097819.
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Hu YZ, Wilson MH, Zong R, Bonnefous C, McMillin DR, Thummel RP. A luminescent Pt(II) complex with a terpyridine-like ligand involving a six-membered chelate ring. Dalton Trans. 2005 Jan 21; (2):354-8. PMID: 15616726.
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Zong R, Naud F, Segal C, Burke J, Wu F, Thummel R. Design and study of Bi[1,8]naphthyridine ligands as potential photooxidation mediators in Ru(II) polypyridyl aquo complexes. Inorg Chem. 2004 Oct 04; 43(20):6195-202. PMID: 15446864.
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Zong R, Thummel RP. 2,9-Di-(2'-pyridyl)-1,10-phenanthroline: a tetradentate ligand for Ru(II). J Am Chem Soc. 2004 Sep 08; 126(35):10800-1. PMID: 15339138.
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Riesgo EC, Hu YZ, Thummel RP. Cu(I) complexes of 3,3'-polymethylene bridged derivatives of 2,2'-bi-1,10-phenanthroline. Inorg Chem. 2003 Oct 20; 42(21):6648-54. PMID: 14552616.
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Hu YZ, Zhang G, Thummel RP. Friedländer approach for the incorporation of 6-bromoquinoline into novel chelating ligands. Org Lett. 2003 Jun 26; 5(13):2251-3. PMID: 12816421.
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Chelucci G, Thummel RP. Chiral 2,2'-bipyridines, 1,10-phenanthrolines, and 2,2':6',2' '-terpyridines: syntheses and applications in asymmetric homogeneous catalysis. Chem Rev. 2002 Sep; 102(9):3129-70. PMID: 12222984.
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Hu YZ, Xiang Q, Thummel RP. Bi-1,10-phenanthrolines and their mononuclear Ru(II) complexes. Inorg Chem. 2002 Jul 01; 41(13):3423-8. PMID: 12079460.
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Hu YZ, Chamchoumis C, Grebowicz JS, Thummel RP. Unique 2:1 complex with a trans-chelating bis-pyridine ligand. Inorg Chem. 2002 Apr 22; 41(8):2296-300. PMID: 11952388.
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Brown D, Muranjan S, Jang Y, Thummel R. Di-[1,10]-phenanthrolinyl diazines: a new family of bis-tridentate chelators. Org Lett. 2002 Apr 18; 4(8):1253-6. PMID: 11950335.
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Bonnefous C, Chouai A, Thummel RP. Cyclometalated complexes of Ru(II) with 2-aryl derivatives of quinoline and 1,10-phenanthroline. Inorg Chem. 2001 Nov 05; 40(23):5851-9. PMID: 11681896.
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Riesgo EC, Hu YZ, Bouvier F, Thummel RP, Scaltrito DV, Meyer GJ. Crowded Cu(I) complexes involving benzo[h]quinoline: pi-stacking effects and long-lives excited states. Inorg Chem. 2001 Jul 02; 40(14):3413-22. PMID: 11421687.
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Riesgo E, Hu YZ, Bouvier F, Thummel RP. Evaluation of diimine ligand exchange on Cu(I). Inorg Chem. 2001 May 21; 40(11):2541-6. PMID: 11350232.
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Gladiali S, Chelucci G, Mudadu MS, Gastaut MA, Thummel RP. Friedländer synthesis of chiral alkyl-substituted 1,10-phenanthrolines. J Org Chem. 2001 Jan 26; 66(2):400-5. PMID: 11429806.
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Nonami H, Wu F, Thummel RP, Fukuyama Y, Yamaoka H, Erra-Balsells R. Evaluation of pyridoindoles, pyridylindoles and pyridylpyridoindoles as matrices for ultraviolet matrix-assisted laser desorption/ionization time-of-flight mass spectrometry. Rapid Commun Mass Spectrom. 2001; 15(23):2354-73. PMID: 11746903.
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Juris A, Prodi L, Harriman A, Ziessel R, Hissler M, el-Ghayoury A, Wu F, Riesgo EC, Thummel RP. Mono- and dinuclear ruthenium(II) and osmium(II) polypyridine complexes built around spiro-bridged bis(phenanthroline) ligands: synthesis, electrochemistry, and photophysics. Inorg Chem. 2000 Aug, 7; 39(16):3590-8. PMID: 11196820.
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Wu F, Chamchoumis CM, Thummel RP. Bidentate ligands that contain pyrrole in place of pyridine. Inorg Chem. 2000 Feb 07; 39(3):584-90. PMID: 11229581.
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Wu F, Riesgo E, Pavalova A, Kipp RA, Schmehl RH, Thummel RP. Ruthenium(II) Complexes of 2-Aryl-1,10-phenanthrolines: Synthesis, Structure, and Photophysical Properties. Inorg Chem. 1999 Nov 29; 38(24):5620-5628. PMID: 11671292.
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Riesgo EC, Credi A, De Cola L, Thummel RP. Diastereoselective Formation and Photophysical Behavior of a Chiral Copper(I) Phenanthroline Complex. Inorg Chem. 1998 May 04; 37(9):2145-2149. PMID: 11670368.
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Jahng Y, Thummel RP, Bott SG. Formation of Ruthenium(II) Complexes with Unsymmetrical Terdentate Ligands. Inorg Chem. 1997 Jul 02; 36(14):3133-3138. PMID: 11669968.
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Riesgo EC, Jin X, Thummel RP. Introduction of Benzo[h]quinoline and 1,10-Phenanthroline Subunits by Friedländer Methodology. J Org Chem. 1996 May 03; 61(9):3017-3022. PMID: 11667162.
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1996 | 1 | 1997 | 1 | 1998 | 1 | 1999 | 1 | 2000 | 2 | 2001 | 5 | 2002 | 4 | 2003 | 2 | 2004 | 3 | 2005 | 4 | 2006 | 4 | 2007 | 5 | 2008 | 8 | 2009 | 4 | 2010 | 7 | 2011 | 4 | 2012 | 8 | 2013 | 7 | 2014 | 3 | 2015 | 5 | 2016 | 3 | 2017 | 1 |
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