 Alkynes
"Alkynes" is a descriptor in the National Library of Medicine's controlled vocabulary thesaurus,
MeSH (Medical Subject Headings). Descriptors are arranged in a hierarchical structure,
which enables searching at various levels of specificity.
Hydrocarbons with at least one triple bond in the linear portion, of the general formula Cn-H2n-2.
| Descriptor ID |
D000480
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| MeSH Number(s) |
D02.455.326.397
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| Concept/Terms |
Alkynes- Alkynes
- Acetylenic Compounds
- Acetylenes
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Below are MeSH descriptors whose meaning is more general than "Alkynes".
Below are MeSH descriptors whose meaning is more specific than "Alkynes".
This graph shows the total number of publications written about "Alkynes" by people in this website by year, and whether "Alkynes" was a major or minor topic of these publications.
To see the data from this visualization as text, click here.
| Year | Major Topic | Minor Topic | Total |
|---|
| 2002 | 1 | 0 | 1 | | 2006 | 1 | 0 | 1 | | 2007 | 0 | 1 | 1 | | 2010 | 1 | 0 | 1 | | 2011 | 2 | 0 | 2 | | 2012 | 0 | 1 | 1 | | 2014 | 1 | 0 | 1 | | 2015 | 1 | 0 | 1 |
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Below are the most recent publications written about "Alkynes" by people in Profiles.
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Le PQ, May JA. Hydrazone-initiated carbene/alkyne cascades to form polycyclic products: ring-fused cyclopropenes as mechanistic intermediates. J Am Chem Soc. 2015 Sep 30; 137(38):12219-22.
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Grigorjeva L, Daugulis O. Cobalt-catalyzed, aminoquinoline-directed C(sp²)-H bond alkenylation by alkynes. Angew Chem Int Ed Engl. 2014 Sep 15; 53(38):10209-12.
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Jansone-Popova S, May JA. Synthesis of bridged polycyclic ring systems via carbene cascades terminating in C-H bond insertion. J Am Chem Soc. 2012 Oct 31; 134(43):17877-80.
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West JD, Stamm CE, Brown HA, Justice SL, Morano KA. Enhanced toxicity of the protein cross-linkers divinyl sulfone and diethyl acetylenedicarboxylate in comparison to related monofunctional electrophiles. Chem Res Toxicol. 2011 Sep 19; 24(9):1457-9.
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Truong T, Daugulis O. Transition-metal-free alkynylation of aryl chlorides. Org Lett. 2011 Aug 19; 13(16):4172-5.
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West JD, Stamm CE, Kingsley PJ. Structure-activity comparison of the cytotoxic properties of diethyl maleate and related molecules: identification of diethyl acetylenedicarboxylate as a thiol cross-linking agent. Chem Res Toxicol. 2011 Jan 14; 24(1):81-8.
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DeBoef B, Counts WR, Gilbertson SR. Rhodium-catalyzed synthesis of eight-membered rings. J Org Chem. 2007 Feb 02; 72(3):799-804.
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Do L, Smith RC, Tennyson AG, Lippard SJ. Luminescent properties of water-soluble conjugated metallopolymers and their application to fluorescent nitric oxide detection. Inorg Chem. 2006 Oct 30; 45(22):8998-9005.
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Gilbertson SR, DeBoef B. Rhodium catalyzed [4 + 2 + 2] cycloaddition and alkyne insertion: a new route to eight-membered rings. J Am Chem Soc. 2002 Jul 31; 124(30):8784-5.
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