P Halasyamani
Title | Professor |
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Institution | University of Houston |
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Department | Chemistry |
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Address | 4800 Calhoun Rd Houston TX 77004
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Phone | 713-743-3278 |
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vCard | Download vCard |
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Bibliographic
Publications listed below are automatically derived from MEDLINE/PubMed and other sources, which might result in incorrect or missing publications.
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Zhang R, Gibbs AS, Zhang W, Halasyamani PS, Hayward MA. Structural Modification of the Cation-Ordered Ruddlesden-Popper Phase YSr2Mn2O7 by Cation Exchange and Anion Insertion. Inorg Chem. 2017 Aug 21; 56(16):9988-9995. PMID: 28777561.
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Wu H, Yu H, Pan S, Halasyamani PS. Deep-Ultraviolet Nonlinear-Optical Material K3Sr3Li2Al4B6O20F: Addressing the Structural Instability Problem in KBe2BO3F2. Inorg Chem. 2017 Aug 07; 56(15):8755-8758. PMID: 28742331.
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Abeysinghe D, Smith MD, Yeon J, Tran TT, Paria Sena R, Hadermann J, Halasyamani PS, Zur Loye HC. Crystal Growth and Structure Analysis of Ce18W10O57: A Complex Oxide Containing Tungsten in an Unusual Trigonal Prismatic Coordination Environment. Inorg Chem. 2017 Mar 06; 56(5):2566-2575. PMID: 28199086.
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Tran TT, Koocher NZ, Rondinelli JM, Halasyamani PS. Beryllium-Free ß-Rb2 Al2 B2 O7 as a Possible Deep-Ultraviolet Nonlinear Optical Material Replacement for KBe2 BO3 F2. Angew Chem Int Ed Engl. 2017 Mar 06; 56(11):2969-2973. PMID: 28140509.
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Tran TT, Young J, Rondinelli JM, Halasyamani PS. Mixed-Metal Carbonate Fluorides as Deep-Ultraviolet Nonlinear Optical Materials. J Am Chem Soc. 2017 Jan 25; 139(3):1285-1295. PMID: 28013546.
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Geng L, Li Q, Lu H, Dai K, Halasyamani PS. Sb-Based antiferromagnetic oxychlorides: MSb2O3(OH)Cl (M = Mn, Fe, Co) with 2D spin-dimer structures. Dalton Trans. 2016 Nov 15; 45(45):18183-18189. PMID: 27792225.
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Khatri NM, Pablico-Lansigan MH, Boncher WL, Mertzman JE, Labatete AC, Grande LM, Wunder D, Prushan MJ, Zhang W, Halasyamani PS, Monteiro JH, Bettencourt-Dias A, Stoll SL. Luminescence and Nonlinear Optical Properties in Copper(I) Halide Extended Networks. Inorg Chem. 2016 Nov 07; 55(21):11408-11417. PMID: 27735188.
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Zhang R, Abbett BM, Read G, Lang F, Lancaster T, Tran TT, Halasyamani PS, Blundell SJ, Benedek NA, Hayward MA. La2SrCr2O7: Controlling the Tilting Distortions of n = 2 Ruddlesden-Popper Phases through A-Site Cation Order. Inorg Chem. 2016 Sep 06; 55(17):8951-60. PMID: 27505146.
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Yu H, Young J, Wu H, Zhang W, Rondinelli JM, Halasyamani PS. Electronic, Crystal Chemistry, and Nonlinear Optical Property Relationships in the Dugganite A3B3CD2O14 Family. J Am Chem Soc. 2016 Apr 13; 138(14):4984-9. PMID: 27015535.
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Morrison G, Tran TT, Halasyamani PS, zur Loye HC. K8(K5F)U6Si8O40: An Intergrowth Uranyl Silicate. Inorg Chem. 2016 Apr 04; 55(7):3215-7. PMID: 26974872.
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Yu H, Zhang W, Young J, Rondinelli JM, Halasyamani PS. Bidenticity-Enhanced Second Harmonic Generation from Pb Chelation in Pb3Mg3TeP2O14. J Am Chem Soc. 2016 Jan 13; 138(1):88-91. PMID: 26687636.
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Yu H, Zhang W, Young J, Rondinelli JM, Halasyamani PS. Design and Synthesis of the Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material Ba3(ZnB5O10)PO4. Adv Mater. 2015 Dec 02; 27(45):7380-5. PMID: 26459262.
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Tran TT, He J, Rondinelli JM, Halasyamani PS. RbMgCO3F: A New Beryllium-Free Deep-Ultraviolet Nonlinear Optical Material. J Am Chem Soc. 2015 Aug 26; 137(33):10504-7. PMID: 26256148.
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Kim SW, Zhang R, Halasyamani PS, Hayward MA. K4Fe3F12: An Fe(2+)/Fe(3+) Charge-Ordered, Ferrimagnetic Fluoride with a Cation-Deficient, Layered Perovskite Structure. Inorg Chem. 2015 Jul 06; 54(13):6647-52. PMID: 26099033.
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Cortese AJ, Wilkins B, Smith MD, Yeon J, Morrison G, Tran TT, Halasyamani PS, zur Loye HC. Crystal growth of four oxovanadium(IV) tartrates prepared via a mild two-step hydrothermal method: observation of spin-dimer behavior and second harmonic generation. Inorg Chem. 2015 Apr 20; 54(8):4011-20. PMID: 25823416.
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Mandal P, Manjón-Sanz A, Corkett AJ, Comyn TP, Dawson K, Stevenson T, Bennett J, Henrichs LF, Bell AJ, Nishibori E, Takata M, Zanella M, Dolgos MR, Adem U, Wan X, Pitcher MJ, Romani S, Tran TT, Halasyamani PS, Claridge JB, Rosseinsky MJ. Morphotropic Phase Boundary in the Pb-Free (1 - x)BiTi(3/8)Fe(2/8)Mg(3/8)O3-xCaTiO3 System: Tetragonal Polarization and Enhanced Electromechanical Properties. Adv Mater. 2015 May 13; 27(18):2883-9. PMID: 25820793.
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Halasyamani PS. Editorial for the ACS Select collection on solid-state chemistry. Inorg Chem. 2014 Oct 20; 53(20):10781-4. PMID: 25327830.
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Donakowski MD, Gautier R, Lu H, Tran TT, Cantwell JR, Halasyamani PS, Poeppelmeier KR. Syntheses of two vanadium oxide-fluoride materials that differ in phase matchability. Inorg Chem. 2015 Feb 02; 54(3):765-72. PMID: 25137441; PMCID: PMC4317054.
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Amano Patino M, Smith T, Zhang W, Halasyamani PS, Hayward MA. Cation exchange in a 3D perovskite-synthesis of Ni(0.5)TaO3. Inorg Chem. 2014 Aug 04; 53(15):8020-4. PMID: 25050865.
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Tran TT, Halasyamani PS, Rondinelli JM. Role of acentric displacements on the crystal structure and second-harmonic generating properties of RbPbCO3F and CsPbCO3F. Inorg Chem. 2014 Jun 16; 53(12):6241-51. PMID: 24867361; PMCID: PMC4066918.
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Holland M, Donakowski MD, Pozzi EA, Rasmussen AM, Tran TT, Pease-Dodson SE, Halasyamani PS, Seideman T, Van Duyne RP, Poeppelmeier KR. Polar alignment of ?-shaped basic building units within transition metal oxide fluoride materials. Inorg Chem. 2014 Jan 06; 53(1):221-8. PMID: 24328163.
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Luo K, Tran TT, Halasyamani PS, Hayward MA. Synthesis and selective topochemical fluorination of the cation and anion-vacancy ordered phases Ba2YCoO5 and Ba3YCo2O7.5. Inorg Chem. 2013 Dec 02; 52(23):13762-9. PMID: 24229386.
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Retuerto M, Li MR, Ignatov A, Croft M, Ramanujachary KV, Chi S, Hodges JP, Dachraoui W, Hadermann J, Tran TT, Halasyamani PS, Grams CP, Hemberger J, Greenblatt M. Polar and magnetic layered A-site and rock salt B-site-ordered NaLnFeWO6 (Ln = La, Nd) perovskites. Inorg Chem. 2013 Nov 04; 52(21):12482-91. PMID: 24138134.
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Reger DL, Leitner A, Smith MD, Tran TT, Halasyamani PS. Homochiral helical metal-organic frameworks of group 1 metals. Inorg Chem. 2013 Sep 03; 52(17):10041-51. PMID: 23941215.
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Lu H, Gautier R, Donakowski MD, Tran TT, Edwards BW, Nino JC, Halasyamani PS, Liu Z, Poeppelmeier KR. Nonlinear active materials: an illustration of controllable phase matchability. J Am Chem Soc. 2013 Aug 14; 135(32):11942-50. PMID: 23865561.
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Yeon J, Smith MD, Sefat AS, Tran TT, Halasyamani PS, zur Loye HC. U3F12(H2O), a noncentrosymmetric uranium(IV) fluoride prepared via a convenient in situ route that creates U4+ under mild hydrothermal conditions. Inorg Chem. 2013 Aug 05; 52(15):8303-5. PMID: 23834284.
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Li MR, Walker D, Retuerto M, Sarkar T, Hadermann J, Stephens PW, Croft M, Ignatov A, Grams CP, Hemberger J, Nowik I, Halasyamani PS, Tran TT, Mukherjee S, Dasgupta TS, Greenblatt M. Polar and magnetic Mn2FeMO6 (M=Nb, Ta) with LiNbO3-type structure: high-pressure synthesis. Angew Chem Int Ed Engl. 2013 Aug 05; 52(32):8406-10. PMID: 23813619.
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Yeon J, Sefat AS, Tran TT, Halasyamani PS, zur Loye HC. Crystal growth, structure, polarization, and magnetic properties of cesium vanadate, Cs2V3O8: a structure-property study. Inorg Chem. 2013 May 20; 52(10):6179-86. PMID: 23659551.
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Nguyen SD, Halasyamani PS. Synthesis, structure, and characterization of two new polar sodium tungsten selenites: Na2(WO3)3(SeO3)·2H2O and Na6(W6O19)(SeO3)2. Inorg Chem. 2013 Mar 04; 52(5):2637-47. PMID: 23425251.
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Tran TT, Halasyamani PS. New fluoride carbonates: centrosymmetric KPb2(CO3)2F and noncentrosymmetric K2.70Pb5.15(CO3)5F3. Inorg Chem. 2013 Mar 04; 52(5):2466-73. PMID: 23394454.
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Dolgos MR, Adem U, Manjon-Sanz A, Wan X, Comyn TP, Stevenson T, Bennett J, Bell AJ, Tran TT, Halasyamani PS, Claridge JB, Rosseinsky MJ. Perovskite B-Site Compositional Control of [110]p Polar Displacement Coupling in an Ambient-Pressure-Stable Bismuth-based Ferroelectric. Angew Chem Weinheim Bergstr Ger. 2012 Oct 22; 124(43):10928-10933. PMID: 25821252.
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Dolgos MR, Adem U, Manjon-Sanz A, Wan X, Comyn TP, Stevenson T, Bennett J, Bell AJ, Tran TT, Halasyamani PS, Claridge JB, Rosseinsky MJ. Perovskite B-site compositional control of [110]p polar displacement coupling in an ambient-pressure-stable bismuth-based ferroelectric. Angew Chem Int Ed Engl. 2012 Oct 22; 51(43):10770-5. PMID: 23023739.
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Olshansky JH, Tran TT, Hernandez KJ, Zeller M, Halasyamani PS, Schrier J, Norquist AJ. Role of hydrogen-bonding in the formation of polar achiral and nonpolar chiral vanadium selenite frameworks. Inorg Chem. 2012 Oct 15; 51(20):11040-8. PMID: 23003324.
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Oh SJ, Shin Y, Tran TT, Lee DW, Yoon A, Halasyamani PS, Ok KM. Structure-property relationships in solid solutions of noncentrosymmetric Aurivillius phases, Bi(4-x)La(x)Ti3O12 (x = 0-0.75). Inorg Chem. 2012 Oct 01; 51(19):10402-7. PMID: 22984919.
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Nguyen SD, Halasyamani PS. Synthesis, structure, and characterization of new Li+-d0-lone-pair-oxides: noncentrosymmetric polar Li6(Mo2O5)3(SeO3)6 and centrosymmetric Li2(MO3)(TeO3) (M = Mo6+ or W6+). Inorg Chem. 2012 Sep 03; 51(17):9529-38. PMID: 22916963.
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Donakowski MD, Gautier R, Yeon J, Moore DT, Nino JC, Halasyamani PS, Poeppelmeier KR. The role of polar, lamdba (?)-shaped building units in noncentrosymmetric inorganic structures. J Am Chem Soc. 2012 May 09; 134(18):7679-89. PMID: 22335338.
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Yeon J, Kim SH, Nguyen SD, Lee H, Halasyamani PS. Two new noncentrosymmetric (NCS) polar oxides: syntheses, characterization, and structure-property relationships in BaMTe2O7 (M = Mg2+ or Zn2+). Inorg Chem. 2012 Feb 20; 51(4):2662-8. PMID: 22296559.
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Yeon J, Kim SH, Nguyen SD, Lee H, Halasyamani PS. New vanadium selenites: centrosymmetric Ca2(VO2)2(SeO3)3(H2O)2, Sr2(VO2)2(SeO3)3, and Ba(V2O5)(SeO3), and noncentrosymmetric and polar A4(VO2)2(SeO3)4(Se2O5) (A = Sr2+ or Pb2+). Inorg Chem. 2012 Jan 02; 51(1):609-19. PMID: 22145697.
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Queen WL, West JP, Hwu SJ, Tran TT, Halasyamani PS, VanDerveer D. Symmetry preservation in a new noncentrosymmetric lattice comprised of acentric POM clusters residing in bowls of Cs(+)-based half SOD ß-cage. Chem Commun (Camb). 2012 Feb 04; 48(11):1665-7. PMID: 22127106.
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Yeon J, Kim SH, Hayward MA, Halasyamani PS. "A" cation polarity control in ACuTe2O7 (A = Sr2+, Ba2+, or Pb2+). Inorg Chem. 2011 Sep 05; 50(17):8663-70. PMID: 21800873.
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Nguyen SD, Yeon J, Kim SH, Halasyamani PS. BiO(IO3): a new polar iodate that exhibits an aurivillius-type (Bi2O2)2+ layer and a large SHG response. J Am Chem Soc. 2011 Aug 17; 133(32):12422-5. PMID: 21776958.
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Zhu T, Qin J, Halasyamani PS. Synthesis and structure of A4V6[Te2(4+)Te6+]O24 (A = K, Rb)-two new quaternary mixed-valent tellurium oxides. Dalton Trans. 2011 Sep 14; 40(34):8527-32. PMID: 21695319.
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Nguyen SD, Kim SH, Halasyamani PS. Synthesis, characterization, and structure-property relationships in two new polar oxides: Zn2(MoO4)(SeO3) and Zn2(MoO4)(TeO3). Inorg Chem. 2011 Jun 06; 50(11):5215-22. PMID: 21557565.
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Lee DW, Oh SJ, Halasyamani PS, Ok KM. New quaternary tellurite and selenite: synthesis, structure, and characterization of centrosymmetric InVTe2O8 and noncentrosymmetric InVSe2O8. Inorg Chem. 2011 May 16; 50(10):4473-80. PMID: 21486014.
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Kim SW, Chang HY, Halasyamani PS. Selective pure-phase synthesis of the multiferroic BaMF(4) (M = Mg, Mn, Co, Ni, and Zn) family. J Am Chem Soc. 2010 Dec 22; 132(50):17684-5. PMID: 21114317.
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Kim MK, Kim SH, Chang HY, Halasyamani PS, Ok KM. New noncentrosymmetric tellurite phosphate material: synthesis, characterization, and calculations of Te2O(PO4)2. Inorg Chem. 2010 Aug 02; 49(15):7028-34. PMID: 20586470.
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Yeon J, Kim SH, Halasyamani PS. A3V5O14 (A = K+, Rb+, or Tl+), new polar oxides with a tetragonal tungsten bronze related structural topology: synthesis, structure, and functional properties. Inorg Chem. 2010 Aug 02; 49(15):6986-93. PMID: 20608660.
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Choyke SJ, Blau SM, Larner AA, Sarjeant AN, Yeon J, Halasyamani PS, Norquist AJ. Noncentrosymmetry in new templated gallium fluorophosphates. Inorg Chem. 2009 Dec 07; 48(23):11277-82. PMID: 19863070.
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Claridge JB, Hughes H, Bridges CA, Allix M, Suchomel MR, Niu H, Kuang X, Rosseinsky MJ, Bellido N, Grebille D, Perez O, Simon C, Pelloquin D, Blundell SJ, Lancaster T, Baker PJ, Pratt FL, Halasyamani PS. Frustration of magnetic and ferroelectric long-range order in Bi(2)Mn(4/3)Ni(2/3)O(6). J Am Chem Soc. 2009 Oct 07; 131(39):14000-17. PMID: 19746905.
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Choi MH, Kim SH, Chang HY, Halasyamani PS, Ok KM. New noncentrosymmetric material--[N(CH3)4]ZnCl3: polar chains of aligned ZnCl4 tetrahedra. Inorg Chem. 2009 Sep 07; 48(17):8376-82. PMID: 19715372.
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Lekse JW, Moreau MA, McNerny KL, Yeon J, Halasyamani PS, Aitken JA. Second-harmonic generation and crystal structure of the diamond-like semiconductors Li(2)CdGeS(4) and Li(2)CdSnS(4). Inorg Chem. 2009 Aug 17; 48(16):7516-8. PMID: 19621873.
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Chang HY, Kim SH, Ok KM, Halasyamani PS. Polar or nonpolar? A+ cation polarity control in A2Ti(IO3)6 (A = Li, Na, K, Rb, Cs, Tl). J Am Chem Soc. 2009 May 20; 131(19):6865-73. PMID: 19385630.
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Chang HY, Kim SH, Halasyamani PS, Ok KM. Alignment of lone pairs in a new polar material: synthesis, characterization, and functional properties of Li2Ti(IO3)6. J Am Chem Soc. 2009 Feb 25; 131(7):2426-7. PMID: 19192970.
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Halasyamani PS, Poeppelmeier KR. Preface: Overview of the forum on functional inorganic materials. Inorg Chem. 2008 Oct 06; 47(19):8427-8. PMID: 18821808.
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Chang HY, Sivakumar T, Ok KM, Halasyamani PS. Polar hexagonal tungsten bronze-type oxides: KNbW2O9, RbNbW2O9, and KTaW2O9. Inorg Chem. 2008 Oct 06; 47(19):8511-7. PMID: 18821817.
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Marvel MR, Lesage J, Baek J, Halasyamani PS, Stern CL, Poeppelmeier KR. Cation-anion interactions and polar structures in the solid state. J Am Chem Soc. 2007 Nov 14; 129(45):13963-9. PMID: 17944466.
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Chang HY, Ok KM, Kim JH, Halasyamani PS, Stoltzfus M, Woodward P. Synthesis, structure, characterization, and calculations of two new Sn2+ -W6+-oxides, Sn2WO5 and Sn3WO6. Inorg Chem. 2007 Aug 20; 46(17):7005-11. PMID: 17658875.
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Sambrook T, Smura CF, Clarke SJ, Ok KM, Halasyamani PS. Structure and physical properties of the polar oxysulfide CaZnOS. Inorg Chem. 2007 Apr 02; 46(7):2571-4. PMID: 17348643.
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Ok KM, Baek J, Halasyamani PS, O'Hare D. New layered uranium phosphate fluorides: syntheses, structures, characterizations, and ion-exchange properties of A(UO2)F(HPO4).xH2O (A = Cs+, Rb+, K+; x = 0-1). Inorg Chem. 2006 Dec 11; 45(25):10207-14. PMID: 17140228.
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Veltman TR, Stover AK, Narducci Sarjeant A, Ok KM, Halasyamani PS, Norquist AJ. Directed synthesis of noncentrosymmetric molybdates using composition space analysis. Inorg Chem. 2006 Jul 10; 45(14):5529-37. PMID: 16813416.
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Sivakumar T, Ok KM, Halasyamani PS. Synthesis, structure, and characterization of novel two- and three-dimensional vanadates: Ba2.5(VO2)3(SeO3)4.H2O and La(VO2)3(TeO6).3H2O. Inorg Chem. 2006 May 01; 45(9):3602-5. PMID: 16634591.
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Ok KM, Chi EO, Halasyamani PS. Bulk characterization methods for non-centrosymmetric materials: second-harmonic generation, piezoelectricity, pyroelectricity, and ferroelectricity. Chem Soc Rev. 2006 Aug; 35(8):710-7. PMID: 16862271.
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Ok KM, Halasyamani PS. New metal iodates: syntheses, structures, and characterizations of noncentrosymmetric La(IO3)3 and NaYI4O12 and Centrosymmetric beta-Cs2I4O11 and Rb2I6O15(OH)2.H2O. Inorg Chem. 2005 Dec 12; 44(25):9353-9. PMID: 16323920.
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Ok KM, Halasyamani PS. Mixed-metal tellurites: synthesis, structure, and characterization of Na1.4Nb3Te4.9O18 and NaNb3Te4O16. Inorg Chem. 2005 May 30; 44(11):3919-25. PMID: 15907119.
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Ok KM, Halasyamani PS. New d0 transition metal iodates: synthesis, structure, and characterization of BaTi(IO3)6, LaTiO(IO3)5, Ba2VO2(IO3)4.(IO3), K2MoO2(IO3)4, and BaMoO2(IO3)4.H2O. Inorg Chem. 2005 Apr 04; 44(7):2263-71. PMID: 15792461.
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Ok KM, Halasyamani PS. The lone-pair cation I(5+) in a hexagonal tungsten oxide-like framework: synthesis, structure, and second-harmonic generating properties of Cs(2)I(4)O(11). Angew Chem Int Ed Engl. 2004 Oct 18; 43(41):5489-91. PMID: 15484245.
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Ok KM, Halasyamani PS. Asymmetric cationic coordination environments in new oxide materials: synthesis and characterization of Pb(4)Te(6)M(10)O(41) (M = Nb(5+) or Ta(5+)). Inorg Chem. 2004 Jul 12; 43(14):4248-53. PMID: 15236537.
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Ok KM, Orzechowski J, Halasyamani PS. Synthesis, structure, and characterization of two new layered mixed-metal phosphates, BaTeMO4(PO4) (M = Nb5+ or Ta5+. Inorg Chem. 2004 Feb 09; 43(3):964-8. PMID: 14753817.
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Ra HS, Ok KM, Halasyamani PS. Combining second-order Jahn-Teller distorted cations to create highly efficient SHG materials: synthesis, characterization, and NLO properties of BaTeM2O9 (M = Mo6+ or W6+). J Am Chem Soc. 2003 Jul 02; 125(26):7764-5. PMID: 12822970.
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Shehee TC, Sykora RE, Ok KM, Halasyamani PS, Albrecht-Schmitt TE. Hydrothermal preparation, structures, and NLO properties of the rare earth molybdenyl iodates, RE(MoO2)(IO3)4(OH) [RE = Nd, Sm, Eu]. Inorg Chem. 2003 Jan 27; 42(2):457-62. PMID: 12693227.
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Porter Y, Halasyamani PS. Syntheses, structures, and characterization of new lead(II)-tellurium(IV)-oxide halides: Pb3Te2O6X2 and Pb3TeO4X2 (X = Cl or Br). Inorg Chem. 2003 Jan 13; 42(1):205-9. PMID: 12513096.
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Maggard PA, Kopf AL, Stern CL, Poeppelmeier KR, Ok KM, Halasyamani PS. From linear inorganic chains to helices: chirality in the M(pyz)(H(2)O)(2)MoO(2)F(4) (M = Zn, Cd) compounds. Inorg Chem. 2002 Sep 23; 41(19):4852-8. PMID: 12230389.
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Ok KM, Halasyamani PS. Anionic templating: synthesis, structure, and characterization of novel three-dimensional mixed-metal oxychlorides Te(4)M(3)O(15).Cl (M = Nb(5+) or Ta(5+)). Inorg Chem. 2002 Jul 29; 41(15):3805-7. PMID: 12132902.
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Sykora RE, Ok KM, Halasyamani PS, Albrecht-Schmitt TE. Structural modulation of molybdenyl iodate architectures by alkali metal cations in AMoO3(IO3) (A = K, Rb, Cs): a facile route to new polar materials with large SHG responses. J Am Chem Soc. 2002 Mar 06; 124(9):1951-7. PMID: 11866608.
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Halasyamani P, Willis MJ, Stern CL, Lundquist PM, Wong GK, Poeppelmeier KR. Composition Space of the (CuO, (1)/(2)Nb(2)O(5))/(HF)(x)().pyridine/H(2)O System. Structure and Synthesis of [pyH(+)](2)[CuNb(2)(py)(4)O(2)F(10)](2-) and CuNb(py)(4)OF(5). Inorg Chem. 1996 Feb 28; 35(5):1367-1371. PMID: 11666334.
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1996 | 1 | 2002 | 3 | 2003 | 3 | 2004 | 3 | 2005 | 3 | 2006 | 4 | 2007 | 3 | 2008 | 2 | 2009 | 6 | 2010 | 3 | 2011 | 7 | 2012 | 7 | 2013 | 10 | 2014 | 4 | 2015 | 6 | 2016 | 5 | 2017 | 5 |
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